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http://ir.ncue.edu.tw/ir/handle/987654321/10070
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| 題名: | Theoretical Study of the Wanzlick Equilibrium |
| 作者: | Cheng, Mu-Jeng;Lai, Chun-Liang;Hu, Ching-Han |
| 貢獻者: | 化學系 |
| 日期: | 2004
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| 上傳時間: | 2012-05-03T06:17:31Z
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| 出版者: | Taylor & Francis |
| 摘要: | A theoretical study of the tetraaminoethylene–diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the ‘Wanzlick equilibrium’ is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile. |
| 關聯: | Mol. Phys., 102(23-24): 2617-2621 |
| 顯示於類別: | [化學系] 期刊論文
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