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题名: Demetalation of the Regioselective Oxygenation Product of an N-Confused Porphyrin Complex
作者: Hung, C. H.;Wang, S. L.;Ko, J. L.;Peng, C. H.;Hu, Ching-Han;Lee, M. T.
贡献者: 化學系
日期: 2004
上传时间: 2012-05-03T06:17:43Z
出版者: American Institute of Physics
摘要: The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.
關聯: Org. Lett., 6(9): 1393-1396
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