National Changhua University of Education Institutional Repository : Item 987654321/10094
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题名: Preparation of a Reversible Redox-Controlled Cage-Type Molecule Linked by Disulfide Bonds
作者: Horng, Yih-Chern;Lin, Tzung-Lung;Tu, Cheng-Yi;Sung, Ting-Ju;Hsieh, Chang-Chih;Hu, Ching-Han;Lee, Hon Man;Kuo, Ting-Shen
贡献者: 化學系
关键词: Dimerization;Self-assembly;Sulfur;Preorganization
日期: 2009-04
上传时间: 2012-05-03T06:18:09Z
出版者: John Wiley & Sons, Inc.
摘要: A unique trithiol macromolecule, with an intrinsic conformational
propensity for dimerization (cage) instead of oligomerization
upon oxidation, was prepared straightforwardly
through rational design. The quantitative conversion and the
reversibility between the cage and trithiols through redox reactions
were assayed by 1H NMR spectroscopic analysis. The X-ray structure of the synthesized cage-type molecule represents
the first successful example of a redox-controlled reversible
dimeric capsule linked through covalent disulfide
bonds.
關聯: Eur. J. Org. Chem., 2009(10): 1511-1514
显示于类别:[化學系] 期刊論文

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