National Changhua University of Education Institutional Repository : Item 987654321/10094
English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 6507/11669
造訪人次 : 29724352      線上人數 : 554
RC Version 3.2 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
搜尋範圍 進階搜尋

請使用永久網址來引用或連結此文件: http://ir.ncue.edu.tw/ir/handle/987654321/10094

題名: Preparation of a Reversible Redox-Controlled Cage-Type Molecule Linked by Disulfide Bonds
作者: Horng, Yih-Chern;Lin, Tzung-Lung;Tu, Cheng-Yi;Sung, Ting-Ju;Hsieh, Chang-Chih;Hu, Ching-Han;Lee, Hon Man;Kuo, Ting-Shen
貢獻者: 化學系
關鍵詞: Dimerization;Self-assembly;Sulfur;Preorganization
日期: 2009-04
上傳時間: 2012-05-03T06:18:09Z
出版者: John Wiley & Sons, Inc.
摘要: A unique trithiol macromolecule, with an intrinsic conformational
propensity for dimerization (cage) instead of oligomerization
upon oxidation, was prepared straightforwardly
through rational design. The quantitative conversion and the
reversibility between the cage and trithiols through redox reactions
were assayed by 1H NMR spectroscopic analysis. The X-ray structure of the synthesized cage-type molecule represents
the first successful example of a redox-controlled reversible
dimeric capsule linked through covalent disulfide
bonds.
關聯: Eur. J. Org. Chem., 2009(10): 1511-1514
顯示於類別:[化學系] 期刊論文

文件中的檔案:

檔案 大小格式瀏覽次數
index.html0KbHTML722檢視/開啟


在NCUEIR中所有的資料項目都受到原著作權保護.

 


DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - 回饋