English  |  正體中文  |  简体中文  |  Items with full text/Total items : 6487/11649
Visitors : 28482023      Online Users : 69
RC Version 3.2 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
Scope Adv. Search

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/10099

Title: A New Type of Asymmetric Tridentate Pyrrolyl-Linked Pincer Ligand and its Aluminum Dihydride Complexes
Authors: Lien, Yu-Ling;Chang, Ya-Chi;Chuang, Nien-Tsu;Datta, Amitabha;Chen, Shau-Jiun;Hu, Ching-Han;Huang, Wen-Yen;Lin, Chia-Her;Huang, Jui-Hsien
Contributors: 化學系
Date: 2010-01
Issue Date: 2012-05-03T06:18:14Z
Publisher: American Chemical Society
Abstract: The new pyrrolyl-linked pincer-type ligand, [C4H2NH(2-CH2NHtBu)(5-CH2NMe2)] (1), that has been employed conveniently in high yield by treatment of (2-t-butylaminomethyl)pyrrole with 1 equiv of formaldehyde and dimethylamine hydrochloride each in diethylether and its corresponding aluminum derivative, [C4H2N(2-CH2NHtBu)(5-CH2NMe2)]AlH2 (2), that has been generated from Me3N�AlH3 using diethylether as a solvent are described. Furthermore, reactions of 2 with 2 equiv of either 1,3-diphenylpropane-1,3-dione in diethylether or phenyl thioisocyanate in dichloromethane interestingly formed [C4H2N(2-CH2NHtBu)(5-CH2NMe2)]Al(PhCOCHCOPh)2 (3) and [C4H2N(2-CH2NHtBu)(5-CH2NMe2)]Al(SCHNPh)2 (4), respectively, following deprotonation or hydroalumination reaction kinetics under a dry nitrogen environment. All of the compounds have been subjected to the X-ray diffraction technique in the solid state as well as characterized by NMR spectra.
Relation: Inorg. Chem., 49(1): 136-143
Appears in Collections:[化學系] 期刊論文

Files in This Item:

File SizeFormat

All items in NCUEIR are protected by copyright, with all rights reserved.


DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - Feedback