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http://ir.ncue.edu.tw/ir/handle/987654321/10100
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| 題名: | A Water-soluble Ribosyl-based Fluorescent Sensor for Hg2+ and Cu2+ Ions |
| 作者: | Chen, Yi-Bin;Wang, Yan-Jhang;Lin, Yi-Jen;Hu, Ching-Han;Chen, Shau-Jiun;Chir, Jiun-Ly;Wu, An-Tai |
| 貢獻者: | 化學系 |
| 關鍵詞: | Fluorescent sensor;Anthracene;Triazole ring;Water-soluble |
| 日期: | 2010-05
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| 上傳時間: | 2012-05-03T06:18:16Z
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| 出版者: | Elsevier |
| 摘要: | A water-soluble ribosyl-based fluorescent sensor 5 was prepared. The sensor contains an anthracene as the fluorophore and a set of complex groups as recognition sites, which bears two triazole ring spacers linked to two ribosyl carboxylic acids groups. The association constants of 5 in water are 2.15 × 105 M−1 and 9.57 × 104 M−1 for Cu2+ and Hg2+ ions, respectively, and both metals formed complexes with 5 at a 1:1 metal to ligand ratio. The binding of 5 to Cu2+ shows a broad pH range (5–10) and a low detection limit (57 ppb) in water, thus indicating it an efficient and promising cation probe. |
| 關聯: | Carbohydrate Res., 345(7): 956-959 |
| 顯示於類別: | [化學系] 期刊論文
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