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Please use this identifier to cite or link to this item:
http://ir.ncue.edu.tw/ir/handle/987654321/10106
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| Title: | A Sugar-aza-crown Ether-based Fluorescent Sensor for Cu2+ and Hg2+ Ions |
| Authors: | Hsieh, Yu-Chi;Chir, Jiun-Ly;Yang, Shih-Tse;Chen, Shau-Jiun;Hu, Ching-Han;Wu, An-Tai |
| Contributors: | 化學系 |
| Keywords: | Fluorescent sensor;Chemosensor;Pyrene |
| Date: | 2011-05
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| Issue Date: | 2012-05-03T06:18:32Z
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| Publisher: | Elsevier |
| Abstract: | A sugar-aza-crown ether (SAC)-based fluorescent sensor 4 was prepared. It contains a pyrene as the fluorophore and its fluoroionophoric properties toward transition metal ions were investigated. Chemosensor 4 exhibits highly selective recognition toward Cu2+ and Hg2+ ions among a series of tested metal ions in methanol solution. The association constants for 4*Cu2+ and 4*Hg2+ in methanol solution were calculated to be 7.4 × 101 M−1 and 4.4 × 103 M−1, respectively. Chemosensor 4 formed complexes with the Cu2+ or Hg2+ ion at a 1:1 ligand-to-metal ratio with a detection limit of 1.3 × 10−4 M Cu2+ and 1.26 × 10−5 M Hg2+, respectively. |
| Relation: | Carbohydrate Res., 346(7): 978-981 |
| Appears in Collections: | [化學系] 期刊論文
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