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http://ir.ncue.edu.tw/ir/handle/987654321/14234
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| Title: | Thermopower and Co K-edge Studies of Potassium Sodium Cobalt Oxyhydrates Na0.33K0.02(H2O)1.33CoO2-δ and Na0.07K0.21(H2O)0.63CoO2-δ |
| Authors: | Liu, Chia-Jyi;Liao, Chia-Yuan;Wang, Jung-Sheng;Nayak, Pradipta K.;Lin, Zhi-Ru;Sheu, Hwo-Shuenn |
| Contributors: | 物理學系 |
| Date: | 2007-10
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| Issue Date: | 2012-09-10T06:15:18Z
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| Publisher: | American Institute of Physics |
| Abstract: | We report measurements of the thermopower and Co K-edge x-ray absorption spectroscopy on bilayer and monolayer (Na,K)x(H2O)yCoO2−δ. According to the Co K-edge x-ray absorption spectra, the Co oxidation number for bilayer hydrate Na0.33K0.02(H2O)1.33CoO2−δ is higher than that of monolayer hydrate Na0.07K0.21(H2O)0.63CoO2−δ with a chemical shift of 3.5 eV, which is in sharp contrast with Co K-edge x-ray absorption spectroscopy and cerimetric titration results for Nax(H2O)yCoO2−δ, where there is essentially no difference of the oxidation number of Co between bilayer and monolayer sodium cobalt oxyhydrates. According to thermopower analysis, band narrowing is observed when γ-Na0.7CoO2 is transformed to potassium sodium cobalt oxyhydrates. |
| Relation: | Appl. Phys. Lett., 91(14): 142509 |
| Appears in Collections: | [物理學系] 期刊論文
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