English  |  正體中文  |  简体中文  |  Items with full text/Total items : 6487/11649
Visitors : 28535395      Online Users : 606
RC Version 3.2 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
Scope Adv. Search

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/14254

Title: A Simple Approach of Fabricating Thermoelectric γ-NaxCoO2 and Superconductive Nax(H2O)yCoO2-δFilms Using the Sol-gel Spin-coating Method
Authors: Liu, Chia-Jyi;Nayak, Pradipta K.;Chen, Yong-Zhi
Contributors: 物理學系
Keywords: Thermoelectric oxides;sol-gel spin coating;Superconductivity;Electrical resistivity;Thermoelectric power
Date: 2009-11
Issue Date: 2012-09-10T06:16:04Z
Publisher: Elsevier
Abstract: We report a simple approach of fabricating thermoelectric γ-NaxCoO2 film with the c-axis orientation using the sol–gel spin-coating method. The inferred sodium content is x = 0.65 according to the correlation between the c-axis lattice constant and x. Temperature dependence of both the resistivity and thermopower resembles that of the γ-Na0.68CoO2 film grown by the reactive solid-phase epitaxy. The fitted thermopower data show that the bandwidth of γ-NaxCoO2 is found to be ~ 101 meV, being close to the quasi-particle band (70–100 meV) derived from an angle-resolved photoemission study of γ-Na0.7CoO2. These results enable the possibility of low-cost fabrication of γ-NaxCoO2-based thermoelectric film devices. Furthermore, we have also topotactically transformed the of γ-NaxCoO2 film to a superconducting Nax(H2O)yCoO2-δ film with Tc, onset = 4.12 K.
Relation: Thin Solid Films, 518(1): 91-93
Appears in Collections:[物理學系] 期刊論文

Files in This Item:

File SizeFormat

All items in NCUEIR are protected by copyright, with all rights reserved.


DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - Feedback