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題名: A Simple Approach of Fabricating Thermoelectric γ-NaxCoO2 and Superconductive Nax(H2O)yCoO2-δFilms Using the Sol-gel Spin-coating Method
作者: Liu, Chia-Jyi;Nayak, Pradipta K.;Chen, Yong-Zhi
貢獻者: 物理學系
關鍵詞: Thermoelectric oxides;sol-gel spin coating;Superconductivity;Electrical resistivity;Thermoelectric power
日期: 2009-11
上傳時間: 2012-09-10T06:16:04Z
出版者: Elsevier
摘要: We report a simple approach of fabricating thermoelectric γ-NaxCoO2 film with the c-axis orientation using the sol–gel spin-coating method. The inferred sodium content is x = 0.65 according to the correlation between the c-axis lattice constant and x. Temperature dependence of both the resistivity and thermopower resembles that of the γ-Na0.68CoO2 film grown by the reactive solid-phase epitaxy. The fitted thermopower data show that the bandwidth of γ-NaxCoO2 is found to be ~ 101 meV, being close to the quasi-particle band (70–100 meV) derived from an angle-resolved photoemission study of γ-Na0.7CoO2. These results enable the possibility of low-cost fabrication of γ-NaxCoO2-based thermoelectric film devices. Furthermore, we have also topotactically transformed the of γ-NaxCoO2 film to a superconducting Nax(H2O)yCoO2-δ film with Tc, onset = 4.12 K.
關聯: Thin Solid Films, 518(1): 91-93
顯示於類別:[物理學系] 期刊論文


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