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http://ir.ncue.edu.tw/ir/handle/987654321/14761
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| Title: | Metal Imido Complexes (M=Ti, W) Containing 2-(Dimethylaminomethyl) Pyrrole: Synthesis and Crystal Structures of ButN=TiClPy2[2-Me2NCH2(C4H3N)] and PhN=WCl3[2-Me2NCH2(C4H3N)] |
| Authors: | Huang, Jui-Hsien;Chi, Liang-Sheng;Huang, Feng-Mau;Kuo, Pei-Cheng;Lee, Gene-Hsiang;Peng, Shie-Ming |
| Contributors: | 化學系 |
| Keywords: | 2-(Dimethylaminomethyl) pyrrole;Titanium imido complexes;2;2'-Methylene-bis(6-t-butyl-4-mehylphenol);Tungsten imido |
| Date: | 2000-08
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| Issue Date: | 2012-12-10T01:39:20Z
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| Publisher: | 中國化學學會 |
| Abstract: | A ti ta nium imido com plex, ButN=TiClPy2[2-Me2NCH2-(C4H3N)] 1, was syn the sized through me tath e sis
by re act ing ButN=TiCl2Py3 with lith ium 2-(dimethylaminomethyl) pyrrolate (LLi) in di ethyl ether at room tem -
per a ture. The dark brown red crys tals were ob tained from a con cen trated di ethyl ether so lu tion of com pound 1
at -20 C and the monoclinic crys tal shows a dis torted oc ta he dral struc ture with two py ri dines tak ing trans po si -
tions. Hy dro ly sis ButN=TiCl2Py3 with 2,2’-methylene-bis(6-t-butyl-4-methylphenol) (HO~~CH2~~OH) gen -
er ates a bis phenoxide ti ta nium com plex, (O~~CH2~~O)TiCl2Py 2, by elim i nat ing one equiv a lent of ButNH2.
Sim i larly, the re ac tion of LH with PhN=WCl4(OEt2) in di ethyl ether at room tem per a ture gen er ates
PhN=WCl3(L) 3, in mod er ate yield. 3 has been char ac ter ized by NMR spectroscopies and X-ray crys tal log ra -
phy. |
| Relation: | Journal of the Chinese Chemical Society, 47(4B): 895-900 |
| Appears in Collections: | [化學系] 期刊論文
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