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Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/14766

Title: Synthesis and Characterization of Organoaluminum Complexes Containing Bi- or Tridentate Substituted Pyrrole Ligands
Authors: Huang, Jui-Hsien;Chen, Hsing-Jen;Chang, Jr-Chiuan;Zhou, Chong-Chin;Lee, Gene-Hsiang;Peng, Shie-Ming
Contributors: 化學系
Date: 2001
Issue Date: 2012-12-10T01:39:26Z
Publisher: American Chemical Society
Abstract: Reactions of AlCl3 with 1 equiv of LiC4H2N(CH2NMe2)2-2,5 or 2 equiv of LiC4H3N(CH2NMe2)-2 in diethyl ether at 78 C afforded AlCl2C4H2N(CH2NMe2)2-2,5 (1) and AlClC4H3N(CH2NMe2)-2 (2), respectively. Alkylation of 1 with MeLi in diethyl ether generates the aluminum dimethyl complex 3. Compound 2 is thermally unstable and was converted to uncharacterized product in CHCl3 within 2 days at 80 C. Compounds 1, 2, and 3 were characterized by NMR spectroscopy and X-ray structure determination.
Relation: Organometallics, 20(12): 2647-2650
Appears in Collections:[化學系] 期刊論文

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