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http://ir.ncue.edu.tw/ir/handle/987654321/14766
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| Title: | Synthesis and Characterization of Organoaluminum Complexes Containing Bi- or Tridentate Substituted Pyrrole Ligands |
| Authors: | Huang, Jui-Hsien;Chen, Hsing-Jen;Chang, Jr-Chiuan;Zhou, Chong-Chin;Lee, Gene-Hsiang;Peng, Shie-Ming |
| Contributors: | 化學系 |
| Date: | 2001
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| Issue Date: | 2012-12-10T01:39:26Z
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| Publisher: | American Chemical Society |
| Abstract: | Reactions of AlCl3 with 1 equiv of LiC4H2N(CH2NMe2)2-2,5 or 2 equiv of LiC4H3N(CH2NMe2)-2 in diethyl ether at 78 C afforded AlCl2C4H2N(CH2NMe2)2-2,5 (1) and AlClC4H3N(CH2NMe2)-2 (2), respectively. Alkylation of 1 with MeLi in diethyl ether generates the aluminum dimethyl complex 3. Compound 2 is thermally unstable and was converted to uncharacterized product in CHCl3 within 2 days at 80 C. Compounds 1, 2, and 3 were characterized by NMR spectroscopy and X-ray structure determination. |
| Relation: | Organometallics, 20(12): 2647-2650 |
| Appears in Collections: | [化學系] 期刊論文
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