National Changhua University of Education Institutional Repository : Item 987654321/14766
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題名: Synthesis and Characterization of Organoaluminum Complexes Containing Bi- or Tridentate Substituted Pyrrole Ligands
作者: Huang, Jui-Hsien;Chen, Hsing-Jen;Chang, Jr-Chiuan;Zhou, Chong-Chin;Lee, Gene-Hsiang;Peng, Shie-Ming
貢獻者: 化學系
日期: 2001
上傳時間: 2012-12-10T01:39:26Z
出版者: American Chemical Society
摘要: Reactions of AlCl3 with 1 equiv of LiC4H2N(CH2NMe2)2-2,5 or 2 equiv of LiC4H3N(CH2NMe2)-2 in diethyl ether at 78 C afforded AlCl2C4H2N(CH2NMe2)2-2,5 (1) and AlClC4H3N(CH2NMe2)-2 (2), respectively. Alkylation of 1 with MeLi in diethyl ether generates the aluminum dimethyl complex 3. Compound 2 is thermally unstable and was converted to uncharacterized product in CHCl3 within 2 days at 80 C. Compounds 1, 2, and 3 were characterized by NMR spectroscopy and X-ray structure determination.
關聯: Organometallics, 20(12): 2647-2650
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