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Title: Synthesis and Structures of Three, Four, and Six-coordinate Monomeric Tin(II) and Tin(IV) Compounds Containing η2-ketiminate Ligands
Authors: Kao, Hung-Ming;Ho, Shih-Mao;Chen, I-Chun;Kuo, Pei-Cheng;Lin, Che-Yu;Tu, Cheng-Yi;Hu, Ching-Han;Huang, Jui-Hsien;Lee, Gene-Hsiang
Contributors: 化學系
Keywords: Tin;Ketiminate;Oxidative addition
Date: 2008-06
Issue Date: 2012-12-10T01:39:51Z
Publisher: Elsevier
Abstract: A series of Sn(II) and Sn(IV) compounds containing ketiminate ligands were synthesized. Reactions of SnCl2 with 1 or 2 equiv. Li[OCMeCHCMeNAr] (where Ar = 2,6-diisopropylphenyl) generate [OCMeCHCMeNAr]SnCl (1) and [OCMeCHCMeNAr]2Sn (2) in moderate yield, respectively. Similarly, reacting SnCl4 with 2 equiv. Li[OCMeCHCMeNAr] yields a six-coordinated [OCMeCHCMeNAr]2SnCl2 (3). Divalent tin compound 2 can be oxidized with I2 in diethyl ether to generate tetravalent tin compound [OCMeCHCMeNAr]2SnI2 (4) in moderate yield. Compounds 1–4 have been characterized by 1H and 13C NMR spectroscopy and have been analyzed by X-ray crystallography. Theoretical calculation found that the bonding of ketiminate ligands and tin atom in compound 2 has a strong ionic character.
Relation: Inorg. Chim. Acta., 361(9-10): 2792-2798
Appears in Collections:[化學系] 期刊論文

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