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Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/14795

Title: A Doubly End-on Azido-bridged Trinuclear Cu(II) Complex: Synthesis, Spectral and DFT Functional Studies
Authors: Datta, Amitabha;Das, Kuheli;Huang, Wen-Yen;Huang, Jui-Hsien;Liao, Fu-Xing;Hu, Ching-Han
Contributors: 化學系
Keywords: COPPER(II);SCHIFF BASE;AZIDE BRIDGE;X-RAY STRUCTURE
Date: 2011-03
Issue Date: 2012-12-10T01:39:59Z
Publisher: Science Reviews 2000 Ltd
Abstract: A trinuclear, doubly azido-bridged Cu(II) complex, [Cu1.50(L)(N3)3(CH3OH)]2, (LH = [(CH3)2NCH2CH2N=CHC6H3(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent CuII ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.
Relation: Journal of Chemical Research, 35(3): 140-143
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