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NCUEIR > College of Science > Department of Chemistry > NSC Projects > Item 987654321/14799

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/14799

Title:	含氮四芽配位基之鎳 ﹑鉑雙金屬陽離子錯合物的合成與反應 The Syntheses and Reactivity of Bimetallic Palladium and Nickel Cationic Complexes Containing Tetradentate Nitrogen Ligands
Authors:	黃瑞賢
Contributors:	化學系
Keywords:	多芽亞胺配位基;雙核錯合物;縮合;亞胺;二氮雜菲;鎳;鈀 Multidentate imine ligand;Binuclear complex;Condensation;Imine;Phenanthroline;Nickel;Palladium
Date:	1999
Issue Date:	2012-12-10T01:40:19Z
Publisher:	行政院國家科學委員會
Abstract:	當一具有雙配位之單陰電性配位基 2-(dimethylaminomethyl)pyrrole(LH)與WCl4(=NPh)(Et2O)和W(=NtBu)2(NHtBu)2反應時可分別產生WCl3(=NPh)(L)和[W(=NtBu)2L]2O。他們可經由核磁共振及Ｘ光結構法來鑑定。當更進一步讓0[W(=NtBu)2L]2O與少量之H2O反應後可產生一鎢群W4O6(=NtBu)4L4而此化合物亦可經由核磁共振光普及Ｘ光結構法還鑑定。 The reactions of monoanionic bidentate 2-(dimethylaminomethyl)pyrrole(LH) with WCl4(=NPh)(Et2O) and W(=NtBu)2(NHtBu)2 yield WCl3(=NPh)(L) and [W(=NtBu)2L]2O, respectively. Their NMR spectroscopies and X-ray structures are characterized. Further reaction of [W(=NtBu)2L]2O with trace of H2O generates a tungsten cluster, W4O6(=NtBu)4L4 and the compound has been characterized by NMR spectroscopies and X-ray structure determination.
Relation:	國科會計畫, 計畫編號: NSC88-2113-M018-005; 研究期間: 8708-8807
Appears in Collections:	[Department of Chemistry] NSC Projects

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