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Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/14803

Title: 酮胺配位基化合物:合成、鑑定和開環聚合(I)
Ketiminate Complexes---Synthesis, Characterization, and Ring-Opening Polymerization (I)
Authors: 黃瑞賢
Contributors: 化學系
Keywords: 酮胺;鋁氫化合物;二氧化碳;甲醯基
Ketiminate;Aluminum hydride;Carbon dioxide;Formate
Date: 2002
Issue Date: 2012-12-10T01:40:52Z
Publisher: 行政院國家科學委員會
Abstract: 酮胺配位基1 與過量之 LiAlH4 反應產生一鋁氫化合物2。化合物2 再室溫下
於CH2Cl2 中與二氧化碳反應得到一不常見甲醯基錯化合物3.
Reaction of ketiminate ligand 1 with an excess of LiAlH4 generates an aluminum
hydride complex 2, which was ready react with carbon dioxide at room temperature in
dichloromethane to yield a novel aluminum formate complex 3.
Relation: 國科會計畫, 計畫編號: NSC91-2113-M018-001; 研究期間: 9108-9207
Appears in Collections:[化學系] 國科會計畫

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