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http://ir.ncue.edu.tw/ir/handle/987654321/14955
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| Title: | Total Synthesis of Ailanthoidol and Precursor XH14 by Stille Coupling |
| Authors: | Lin, S. Y.;Chen, C. L.;Lee, Yean-Jang |
| Contributors: | 化學系 |
| Date: | 2003-04
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| Issue Date: | 2012-12-10T02:51:50Z
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| Publisher: | American Chemical Society |
| Abstract: | Ailanthoidol 1, which can be isolated from Chinese herbal medicine, is achieved in which the longest linear sequence is only six steps in 48% overall yield from commercially available 5-bromo-2-hydroxy-3-methoxybenzaldehyde. The key transformations in the synthesis are the Stille coupling reactions of benzofuranyl bromide with stannanyl compounds. This synthetic strategy can be modified to give access to a variety of different ailanthoidol and XH14 analogues. |
| Relation: | J. Org. Chem., 68(7): 2968-2971 |
| Appears in Collections: | [化學系] 期刊論文
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