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題名: | Total Synthesis of Ailanthoidol and Precursor XH14 by Stille Coupling |
作者: | Lin, S. Y.;Chen, C. L.;Lee, Yean-Jang |
貢獻者: | 化學系 |
日期: | 2003-04
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上傳時間: | 2012-12-10T02:51:50Z
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出版者: | American Chemical Society |
摘要: | Ailanthoidol 1, which can be isolated from Chinese herbal medicine, is achieved in which the longest linear sequence is only six steps in 48% overall yield from commercially available 5-bromo-2-hydroxy-3-methoxybenzaldehyde. The key transformations in the synthesis are the Stille coupling reactions of benzofuranyl bromide with stannanyl compounds. This synthetic strategy can be modified to give access to a variety of different ailanthoidol and XH14 analogues. |
關聯: | J. Org. Chem., 68(7): 2968-2971 |
顯示於類別: | [化學系] 期刊論文
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