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题名: Total Synthesis of Ailanthoidol and Precursor XH14 by Stille Coupling
作者: Lin, S. Y.;Chen, C. L.;Lee, Yean-Jang
贡献者: 化學系
日期: 2003-04
上传时间: 2012-12-10T02:51:50Z
出版者: American Chemical Society
摘要: Ailanthoidol 1, which can be isolated from Chinese herbal medicine, is achieved in which the longest linear sequence is only six steps in 48% overall yield from commercially available 5-bromo-2-hydroxy-3-methoxybenzaldehyde. The key transformations in the synthesis are the Stille coupling reactions of benzofuranyl bromide with stannanyl compounds. This synthetic strategy can be modified to give access to a variety of different ailanthoidol and XH14 analogues.
關聯: J. Org. Chem., 68(7): 2968-2971
显示于类别:[化學系] 期刊論文


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