National Changhua University of Education Institutional Repository : Item 987654321/15028
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题名: Polyhydroxylated Indolines and Oxindoles from C-Glycosides via Sequential Henry Reaction, Michael Addition, and Reductive Amination/Amidation
作者: Zou, Wei;Wu, An-Tai;Bhasin, Milan;Sandbhor, Mahendra;Wu, Shih-Hsiung
贡献者: 化學系
日期: 2007-03
上传时间: 2013-01-07T01:47:47Z
出版者: American Chemical Society
摘要: 6-Nitro-2‘-carbonyl-C-glycofuranosides synthesized via Henry reaction from 1-C-allyl 5-aldo-C-glycoside underwent an intramolecular Michael addition to afford nitrocyclohexanol derivatives in good to excellent yield. Reduction of the nitro group followed by intramolecular amination with ketone and aldehyde and amidation with ester produced indoline and oxindole derivatives, respectively, in excellent yield.
關聯: J. Org. Chem., 72(7): 2686-2689
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