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Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/15255

Title: Finite-conical-well Model for Vertically Adsorbed Diatomic Molecules
Authors: Shih, Yu-Tai;Chuu, D. S.;Mei, W. N.
Contributors: 物理學系
Date: 1995-05
Issue Date: 2013-01-07T09:25:27Z
Publisher: The American Physical Society
Abstract: We present studies of the rotational spectra of a diatomic molecule adsorbed vertically on a solid surface. The hindrance configuration was modeled as a rigid rotor whose spatial motion was confined by a finite conical well. The eigenfunctions can be expressed analytically in terms of the hypergeometric functions, and eigenvalues were solved numerically. We found that the rotational energy levels and the confinement probabilities exhibit oscillatory behaviors when plotted as functions of the hindrance angle. The solutions were used to calculate the rotational-state distribution of the suddenly unhindered rotors and general features which agree with the previous experimental findings were obtained.
Relation: Phys. Rev. B, 51(20): 14626-14635
Appears in Collections:[物理學系] 期刊論文

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