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题名: Orbital-resolved Soft-x-ray Spectroscopy in NaV2O5
作者: Zhang, G. P.;G. T. Woods;Eric L. Shirley;T. A. Callcott;Lin, Lin;Chang, G. S.;B. C. Sales;D. Mandrus;He, J.
贡献者: 物理學系
日期: 2002
上传时间: 2013-06-05T07:59:16Z
出版者: The American Physical Society
摘要: We demonstrate that angle-resolved soft x-ray spectroscopy can resolve absorption by inequivalent oxygen sites and by different orbitals belonging to the same site in NaV2O5. By rotating the polarization direction, we see a dramatic change in the absorption spectra at the oxygen K edge. Our theory identifies the detailed composition of the spectra and predicts a correct energy ordering of the orbitals of three inequivalent oxygen atoms. Because different orbitals dominate absorption spectra at different energies and angles, one can excite at a specific site and “orbital.” In contrast, absorption at the vanadium L edge does not show large changes when varying the polarization direction. The reason for this is that different excitation channels (involving different initial states for the excited electron) overlap in energy and vary in compensating ways, obscuring each channel’s sensitive polarization dependence.
關聯: Physical Review B, 65(16): 165107
显示于类别:[物理學系] 期刊論文

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