Loading...
|
Please use this identifier to cite or link to this item:
http://ir.ncue.edu.tw/ir/handle/987654321/16873
|
| Title: | Phenyl-Carbonyl Coupling Reactions Promoted by Samarium Diiodide and Hexamethylphosphoramide |
| Authors: | Shiue, Jiann-Shyng;Lin, Mei-Huey;Fang, Jim-Min |
| Contributors: | 化學系 |
| Date: | 1997-07
|
| Issue Date: | 2013-06-06T02:33:18Z
|
| Publisher: | American Chemical Society |
| Abstract: | By mediation of samarium diiodide and hexamethylphosphoramide, benzaldehydes and acetophenones underwent self- and cross-couplings to give the products having linkages at the para-carbons of phenyl rings and the carbonyl groups. The phenyl−carbonyl coupling of 2,5-dimethoxybenzaldehyde generated a Sm(III)−enolate intermediate, which was trapped by alkyl halides in a stereospecific manner to give uncommon 1,4-dialkyl-2,5-cyclohexadiene-1-carboxaldehydes. The benzaldehydes bearing tethered carbonyl chains proceeded with intramolecular phenyl−carbonyl couplings to afford fused benzocycles. |
| Relation: | The Journal of Organic Chemistry, 62(14): 4643-4649 |
| Appears in Collections: | [化學系] 期刊論文
|
Files in This Item:
| File |
Size | Format | |
|---|
| index.html | 0Kb | HTML | 580 | View/Open |
|
All items in NCUEIR are protected by copyright, with all rights reserved.
|
