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Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18871

Title: Synthesis of the Chiral Triphosphine (S,S)-PhP(CH2CHMeCH2PPh2)2 and Its Metal Complexes
Authors: Jia, Guochen;Lee, Hon Man;Ian D. Williams
Contributors: 化學系
Date: 1996-10
Issue Date: 2014-08-14T04:28:22Z
Publisher: American Chemical Society
Abstract: The chiral triphosphine ligand (S,S)-PhP(CH2CHMeCH2PPh2)2, ttp*, was synthesized by the reaction of (S)-Ph2PCH2CHMeCH2Cl and PhPH2 in the presence of LDA. Reactions of ttp* with RuCl2(PPh3)3, [RhCl(COD)]2, and CoCl2 produced RuCl2(ttp*), RhCl(ttp*), and CoCl2(ttp*), respectively. These compounds were characterized by elemental analysis and multinuclear NMR spectroscopy. The structure of RhCl(ttp*) has been determined by X-ray diffraction.
Relation: Organometallics, 15(20): 4235-4239
Appears in Collections:[化學系] 期刊論文

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