National Changhua University of Education Institutional Repository : Item 987654321/18871

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NCUEIR > College of Science > Department of Chemistry > Periodical Articles > Item 987654321/18871

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18871

Title:	Synthesis of the Chiral Triphosphine (S,S)-PhP(CH2CHMeCH2PPh2)2 and Its Metal Complexes
Authors:	Jia, Guochen;Lee, Hon Man;Ian D. Williams
Contributors:	化學系
Date:	1996-10
Issue Date:	2014-08-14T04:28:22Z
Publisher:	American Chemical Society
Abstract:	The chiral triphosphine ligand (S,S)-PhP(CH2CHMeCH2PPh2)2, ttp, was synthesized by the reaction of (S)-Ph2PCH2CHMeCH2Cl and PhPH2 in the presence of LDA. Reactions of ttp with RuCl2(PPh3)3, [RhCl(COD)]2, and CoCl2 produced RuCl2(ttp), RhCl(ttp), and CoCl2(ttp), respectively. These compounds were characterized by elemental analysis and multinuclear NMR spectroscopy. The structure of RhCl(ttp) has been determined by X-ray diffraction.
Relation:	Organometallics, 15(20): 4235-4239
Appears in Collections:	[Department of Chemistry] Periodical Articles

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