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NCUEIR > College of Science > Department of Chemistry > Periodical Articles > Item 987654321/18872

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18872

Title:	Coupling Reactions of Terminal Acetylenes with a Cyclometalated Aryl Ligand
Authors:	Jia, Guochen;Lee, Hon Man;Xia, Hai-Ping;Ian D. Williams
Contributors:	化學系
Date:	1996-12
Issue Date:	2014-08-14T04:28:23Z
Publisher:	American Chemical Society
Abstract:	Reaction of RuCl2(PPh3)3 with 1,3-(PPh2CH2)2C6H4 in refluxing 2-propanol produced RuCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3). Reaction of RuCl(PPh3)(PCP) with PhCCH gave the unusual coupling product RuCl(PPh3){η4-CHPhC-2,6-(PPh2CH2)2C6H3}, which has been characterized by X-ray diffraction. Coupling also occurred between RuCl(PPh3)(PCP) and HCCC(OH)(Ph)CH3 to give RuCl(PPh3){η4-CH2CPhCHC-2,6-(PPh2CH2)2C6H3}.
Relation:	Organometallics, 15(26): 5453-5455
Appears in Collections:	[Department of Chemistry] Periodical Articles

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