National Changhua University of Education Institutional Repository : Item 987654321/18874

English | 正體中文 | 简体中文 | Items with full text/Total items : 6507/11669
Visitors : 30058464 Online Users : 632

RC Version 3.2 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.

Scope Adv. Search

Login ‧ Upload ‧ Help ‧ About ‧ Administer

NCUEIR > College of Science > Department of Chemistry > Periodical Articles > Item 987654321/18874

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18874

Title:	Synthesis, Characterization, and Acidity Properties of [MCl(H2)(L)(PMP)]BF4 (M = Ru, L = PPh3, CO;M = Os, L = PPh3;PMP = 2,6-(Ph2PCH2)2C5H3N)
Authors:	Jia, Guochen;Lee, Hon Man;Ian D. Williams;Lau, Chak-Po;Chen, Yuzhong
Contributors:	化學系
Date:	1997-09
Issue Date:	2014-08-14T04:28:25Z
Publisher:	American Chemical Society
Abstract:	Treatment of RuCl2(PPh3)3 with PMP (PMP = 2,6-(Ph2PCH2)2C5H3N) in acetone produced RuCl2(PPh3)(PMP), which has been characterized by X-ray diffraction. Treatment of RuCl2(PPh3)(PMP) with NaBH4 in methanol gave RuHCl(PPh3)(PMP), acidification of which with HBF4�Et2O produced the molecular dihydrogen complex [RuCl(H2)(PPh3)(PMP)]BF4. Treatment of RuHCl(CO)(PPh3)3 with PMP in benzene produced RuHCl(CO)(PMP), which reacted with HBF4�Et2O to give the molecular dihydrogen complex [RuCl(H2)(CO)(PMP)]BF4. The osmium molecular dihydrogen complex [OsCl(H2)(PPh3)(PMP)]BF4 was prepared by protonation of OsHCl(PPh3)(PMP) with HBF4�Et2O. Relative acidities of the dihydrogen complexes were investigated by NMR spectroscopy of equilibrium reactions conducted in CD2Cl2. [RuCl(H2)(CO)(PMP)]BF4 is more acidic than [RuCl(H2)(PPh3)(PMP)]BF4, which is in turn more acidic than its osmium analog [OsCl(H2)(PPh3)(PMP)]BF4.
Relation:	Organometallics, 16(18): 3941-3949
Appears in Collections:	[Department of Chemistry] Periodical Articles

Files in This Item:

File	Size	Format
index.html	0Kb	HTML	546	View/Open