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Title: Preparation and Catalytic Hydrogenation Properties of Some Rhodium and Ruthenium Complexes with Chiral Tridentate Phosphine Ligands (S, S)-PhP(CH2CHMeCH2PPh2)2 and (S)-Ph2PCH2CH(PPh2)CH2CH2PPh2
Authors: Lee, Hon Man;Yang, Chuluo;Jia, Guochen
Contributors: 化學系
Date: 2000-04
Issue Date: 2014-08-14T04:28:33Z
Publisher: Elsevier
Abstract: Treatment of RhCl(ttp*) (ttp*=(S,S)-PhP(CH2CHMeCH2PPh2)2) with NaBH4 produced Rh(BH4)(ttp*). The reaction of RuCl2(ttp*) with NaBH4 produced RuH(BH4)(ttp*). The complexes RhCl(ttp*), RuCl2(ttp*), Rh(BH4)(ttp*), and RuH(BH4)(ttp*) were found to be catalytically active for the hydrogenation of α-acetamidocinnamic acid.
Relation: Journal of Organometallic Chemistry, 601(2): 330-334
Appears in Collections:[Department of Chemistry] Periodical Articles

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