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Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18887

Title: Highly Efficient Heck Reactions of Aryl Bromides with n-Butyl Acrylate Mediated by a Palladium/Phosphine-Imidazolium Salt System
Authors: Yang, Chuluo;Lee, Hon Man;Steven P. Nolan
Contributors: 化學系
Date: 2001-05
Issue Date: 2014-08-14T04:28:38Z
Publisher: American Chemical Society
Abstract: A new phosphine−imidazolium salt, L·HBr (1, L = (1-ethylenediphenylphosphino-3-(mesityl))imidazol-2-ylidene), has been prepared. A combination of 0.5 mol % of Pd(dba)2 and 0.5 mol % of L·HBr in the presence of 2 equiv of Cs2CO3 as base has proven to be highly efficient in the Heck coupling reactions of aryl bromides (from electron-deficient to electron-rich aryl bromides) with n-butyl acrylate.
Relation: Organic Letters, 3(10): 1511-1514
Appears in Collections:[化學系] 期刊論文

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