English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 6507/11669
造訪人次 : 29717379      線上人數 : 373
RC Version 3.2 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
搜尋範圍 進階搜尋

請使用永久網址來引用或連結此文件: http://ir.ncue.edu.tw/ir/handle/987654321/18890

題名: Bis-alkoxycarbonylation of Styrene by Pyridinimine Palladium Catalysts
作者: Claudio Bianchini;Lee, Hon Man;Giuseppe Mantovani;Andrea Meli;Werner Oberhauser
貢獻者: 化學系
日期: 2002
上傳時間: 2014-08-14T04:28:41Z
出版者: Royal Society of Chemistry
摘要: Pyridinimine-modified Pd(II) complexes of general formulae (N-N′)Pd(Y)2 catalyze the methoxycarbonylation of styrene to give dimethyl phenylsuccinate as the largely major product [N-N′=py-2-C(R)N(2,6-R′C6H3), R=H, Me; R′=Me, i-Pr; 6-Mepy-2-C(H)N[2,6-(i-Pr)2C6H3]; py-2-C(H)N(C6H5); Y=acetate, trifluoroacetate]. The influence of various catalytic parameters on the overall conversion of styrene to carbonylated products and on the product selectivity has been studied by systematically varying the type of palladium initiator, the concentrations of organic oxidant (1,4-benzoquinone) and protic acid (p-toluenesulfonic acid), and the CO pressure. By an appropriate choice of the structure of the pyridinimine ligand and of the reaction parameters, turn-over numbers as high as 96 and selectivities in dimethyl phenylsuccinate as high as 98% were obtained. In particular, the overall conversion of styrene is controlled by the steric properties of the alkyl substituents on the imine aryl group, while the nature of the substituent (H or Me) on the imine carbon influences the selectivity. The addition of 2 equivalents of TsOH to the catalytic mixtures generally increased the styrene conversion but lowered the selectivity in dimethyl phenylsuccinate due to greater production of methyl 3,6-diphenyl-4-oxohexanoate. Further additions of TsOH (up to 6 equivalents) resulted in better selectivities and lower conversions for all precursors.
關聯: New Journal of Chemistry, 26(4): 387-397
顯示於類別:[化學系] 期刊論文

文件中的檔案:

檔案 大小格式瀏覽次數
index.html0KbHTML533檢視/開啟


在NCUEIR中所有的資料項目都受到原著作權保護.

 


DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - 回饋