National Changhua University of Education Institutional Repository : Item 987654321/18892
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题名: A Symmetric Derivative of the Trimetallic Nitride Endohedral Metallofullerenes, Sc3N@C80
作者: Erick B. Iezzi;James C. Duchamp;Kim Harich;Tom E. Glass;Lee, Hon Man;Marilyn M. Olmstead;Alan L. Balch;Harry C. Dorn
贡献者: 化學系
日期: 2002-01
上传时间: 2014-08-14T04:28:42Z
出版者: American Chemical Society
摘要: The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.
關聯: Journal of the American Chemical Society, 124(4): 524-525
显示于类别:[化學系] 期刊論文

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