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NCUEIR > College of Science > Department of Chemistry > Periodical Articles > Item 987654321/18903

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18903

Title:	Sc3N@C68 : Folded Pentalene Coordination in an Endohedral Fullerene that Does Not Obey the Isolated Pentagon Rule
Authors:	Marilyn M. Olmstead;Lee, Hon Man;James C. Duchamp;Steven Stevenson;Daniela Marciu;Harry C. Dorn;Alan L. Balch
Contributors:	化學系
Date:	2003-02
Issue Date:	2014-08-14T04:28:50Z
Publisher:	John Wiley & Sons, Inc.
Abstract:	Breaking the rule: The structure of Sc3N@C68⋅[NiII(OEP)]⋅2 C6H6 has been determined by single-crystal X-ray diffraction. The fullerene cage exists as an isomer with D3 symmetry (see picture), as initially predicted by density functional calculations. The scandium atoms are located over the centers of three pentalene units within the three-cornered carbon cage, which cannot obey the isolated pentagon rule. OEP=Octaethylporphyrinate.
Relation:	Angewandte Chemie International Edition, 42(8): 900-903
Appears in Collections:	[Department of Chemistry] Periodical Articles

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