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http://ir.ncue.edu.tw/ir/handle/987654321/18974
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Title: | Dichlorido{N'-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-k2N',O}copper(II) |
Authors: | Amitabha Datta;Kuheli Das;Jhou, Yan-Ming;Huang, Jui-Hsien;Lee, Hon Man |
Contributors: | 化學系 |
Date: | 2011-01
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Issue Date: | 2014-08-14T04:30:27Z
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Publisher: | International Union of Crystallography |
Abstract: | In the title compound, [CuCl2(C9H11N3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) �. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) �]. Intermolecular N-HCl and C-HCl hydrogen bonds link the complexes into a three-dimensional network. |
Relation: | Acta Crystallographica Section E, E67: m123 |
Appears in Collections: | [化學系] 期刊論文
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