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題名: Dichlorido{N'-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-k2N',O}copper(II)
作者: Amitabha Datta;Kuheli Das;Jhou, Yan-Ming;Huang, Jui-Hsien;Lee, Hon Man
貢獻者: 化學系
日期: 2011-01
上傳時間: 2014-08-14T04:30:27Z
出版者: International Union of Crystallography
摘要: In the title compound, [CuCl2(C9H11N3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) �. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) �]. Intermolecular N-HCl and C-HCl hydrogen bonds link the complexes into a three-dimensional network.
關聯: Acta Crystallographica Section E, E67: m123
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