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NCUEIR > College of Science > Department of Chemistry > Periodical Articles > Item 987654321/18974

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/18974

Title:	Dichlorido{N'-[1-(2-pyridin-2-yl)ethylidene]acetohydrazide-k2N',O}copper(II)
Authors:	Amitabha Datta;Kuheli Das;Jhou, Yan-Ming;Huang, Jui-Hsien;Lee, Hon Man
Contributors:	化學系
Date:	2011-01
Issue Date:	2014-08-14T04:30:27Z
Publisher:	International Union of Crystallography
Abstract:	In the title compound, [CuCl2(C9H11N3O)], the CuII atom is in a distorted square-pyramidal CuCl2N2O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) �. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) �]. Intermolecular N-HCl and C-HCl hydrogen bonds link the complexes into a three-dimensional network.
Relation:	Acta Crystallographica Section E, E67: m123
Appears in Collections:	[Department of Chemistry] Periodical Articles

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