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Title: Demetalation of the Regioselective Oxygenation Product of an N-Confused Porphyrin Complex
Authors: Hung, C. H.;Wang, S. L.;Ko, J. L.;Peng, C. H.;Hu, Ching-Han;Lee, M. T.
Contributors: 化學系
Date: 2004
Issue Date: 2012-05-03T06:17:43Z
Publisher: American Institute of Physics
Abstract: The demetalation of MIII(HCTPPO)Br (M = Mn or Fe) afforded two hydroxylated N-confused porphyrinoids. CTPPOH retains the tautomer form of the N-confused porphyrin with a hydroxyl group substituted in the inner-core carbon. The further attack of OH- to the meso carbon afforded a dihydroxylated N-confused macrocycle, CTPP(OH)2.
Relation: Org. Lett., 6(9): 1393-1396
Appears in Collections:[Department of Chemistry] Periodical Articles

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