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題名: | Regioselective Hydroxylation of 2-hydroxychalcones by Dimethyldioxirane Towards Polymethoxylated Flavonoids |
作者: | Chu, H. W.;Wu, H. T.;Lee, Yean-Jang |
貢獻者: | 化學系 |
日期: | 2004-03
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上傳時間: | 2012-12-10T02:51:51Z
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出版者: | Elsevier |
摘要: | The flavone nucleus is part of a large number of natural products and medicinal compounds. In this presentation the novel regioselective hydroxylation of hydroxyarenes with DMD is described. The results showed further that flavonoids with 5-hydroxy group were selectively oxyfunctionalized at the para-position C8 carbon atom by DMD. Finally, according to this methodology, the naturally occurring isosinensetin, tangeretin, sinensetin, nobiletin, natsudaidain, gardenin B, 3,3′,4′,5,6,7,8-heptamethoxyflavone, quercetin and its derivatives were synthesized. The novel regioselective hydroxylation of 2-hydroxychalcones with DMD is described. Based upon this methodology, the polymethoxylated flavonoids are synthesized. |
關聯: | Tetrahedron, 60(11): 2647-2655 |
顯示於類別: | [化學系] 期刊論文
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