National Changhua University of Education Institutional Repository : Item 987654321/16581

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NCUEIR > College of Science > Department of Physics > Periodical Articles > Item 987654321/16581

Please use this identifier to cite or link to this item: http://ir.ncue.edu.tw/ir/handle/987654321/16581

Title:	Thermodynamics of the System of Distinguishable Particles
Authors:	Cheng, Chi-Ho
Contributors:	物理學系
Keywords:	Entropy;Gibbs paradox;Distinguishable particles
Date:	2009
Issue Date:	2013-05-28T07:12:28Z
Publisher:	MDPI Publishing
Abstract:	The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the entropy is not extensive. The inextensivity leads to the so-called Gibbs paradox in which the mixing entropy of two identical classical gases increases. Lots of literature from different points of view were created to resolve the paradox. In this paper, starting from the Boltzmann entropy, we present the thermodynamics of the system of distinguishable particles. A straightforward way to get the corrected Boltzmann counting is shown. The corrected Boltzmann counting factor can be justified in classical statistical mechanics.
Relation:	Entropy, 11(3): 326-333
Appears in Collections:	[Department of Physics] Periodical Articles

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