National Changhua University of Education Institutional Repository : Item 987654321/16581
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题名: Thermodynamics of the System of Distinguishable Particles
作者: Cheng, Chi-Ho
贡献者: 物理學系
关键词: Entropy;Gibbs paradox;Distinguishable particles
日期: 2009
上传时间: 2013-05-28T07:12:28Z
出版者: MDPI Publishing
摘要: The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the entropy is not extensive. The inextensivity leads to the so-called Gibbs paradox in which the mixing entropy of two identical classical gases increases. Lots of literature from different points of view were created to resolve the paradox. In this paper, starting from the Boltzmann entropy, we present the thermodynamics of the system of distinguishable particles. A straightforward way to get the corrected Boltzmann counting is shown. The corrected Boltzmann counting factor can be justified in classical statistical mechanics.
關聯: Entropy, 11(3): 326-333
显示于类别:[物理學系] 期刊論文

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